| ABSTRACT | 第1-6页 |
| DEDICATION | 第6-7页 |
| ACKNOWLEDGMENTS | 第7-8页 |
| TABLE OF CONTENTS | 第8-12页 |
| LIST OF FIGURES | 第12-14页 |
| LIST OF TABLES | 第14-15页 |
| NOMENCLATURE | 第15-23页 |
| Chapter Ⅰ:Introduction | 第23-31页 |
| ·Background and statement of problem | 第23-24页 |
| ·Review of literature | 第24-29页 |
| ·Brief overview of distillation process | 第29-31页 |
| Chapter Ⅱ:Fundamental theory incorporating with modeling of distillation columns | 第31-58页 |
| ·Fundamental theory related to modeling of transfer process | 第31-46页 |
| ·Derivation of the Maxwell-Stefan equation | 第31-37页 |
| ·The Maxwell-Stefan equations for multicomponent system | 第37-38页 |
| ·Matrix formulation of the Maxwell-Stefan equation | 第38-39页 |
| ·Matrix formulation of the Maxwell-Stefan equations for nonideal fluid | 第39-42页 |
| ·The generalized Maxwell-Stefan formulation of irreversible thermodynamics | 第42-46页 |
| ·Estimation of diffusion coefficient | 第46-54页 |
| ·Estimation of Fick diffusion coefficient for multicomponent liquid mixture | 第49-51页 |
| ·Estimation of MS diffusion coefficient for multicomponent liquid mixture | 第51-52页 |
| ·Relationship between Fick and Maxwell-Stefan diffusion coefficients | 第52-54页 |
| ·Film theory | 第54-58页 |
| ·The film model | 第54-55页 |
| ·Multicomponent film model for nonideal fluid system | 第55-58页 |
| Chapter Ⅲ:Mathematic modeling extractive distillation columns and numerical analyzing | 第58-121页 |
| ·Simulation procedure | 第58-62页 |
| ·Mathematic modeling multicomponent distillation | 第62-64页 |
| ·Equilibrium model | 第64-66页 |
| ·Nonequilibrium model incorporating with Maxwell-Stefan theory | 第66-76页 |
| ·The conservation equation | 第69-70页 |
| ·The rate equations | 第70-72页 |
| ·Mass flux for bulk liquid and vapor | 第72-73页 |
| ·The interface equilibrium | 第73-74页 |
| ·The hydraulic equations | 第74页 |
| ·Condensers and reboiler | 第74-75页 |
| ·Initial and boundary conditions for simulation | 第75-76页 |
| ·Thermodynamic property and estimation of transfer coefficients | 第76-103页 |
| ·Estimation of thermodynamic factor from activity coefficient models | 第76-78页 |
| ·Thermodynamic factors for multicomponent system | 第78-82页 |
| ·Mass transfer coefficient | 第82-86页 |
| ·Multicomponent mass transfer coefficient | 第86-88页 |
| ·Correlation for mass transfer coefficient | 第88-90页 |
| ·Estimation of mass transfer coefficient from empirical correlations | 第90-93页 |
| ·Heat transfer coefficient | 第93-96页 |
| ·Correlation for heat transfer coefficient:Chilton and Colburn method | 第96-97页 |
| ·Correlation for effective interfacial area, heat and mass transfer coefficient | 第97-100页 |
| ·The bootstrap problem and its solution | 第100-103页 |
| ·Simutaneous heat and mass transfer | 第103-114页 |
| ·Mathematical analogies among mass, heat and momentum transfer | 第103-106页 |
| ·Physical equalities among mass, heat and momentum transfer | 第106-109页 |
| ·Balance equations for simultaneous heat and mass transfer | 第109-110页 |
| ·Constitutive relations for simultaneous heat and mass transfer | 第110-112页 |
| ·Models for simultaneous mass and energy transfer | 第112-114页 |
| ·Numerical analysis | 第114-121页 |
| ·Newton's method and algorithm for Newton's method | 第114-116页 |
| ·Variables and equations for the nonequilibrium models | 第116-118页 |
| ·Convergence analyzing and solving of model equations | 第118-121页 |
| Chapter Ⅳ:Simulation results and discussion | 第121-146页 |
| ·The temperature profiles and results of temperature regession | 第121-124页 |
| ·The effective diffusivity and diffusion coefficients | 第124-128页 |
| ·Murphree vapor efficiency | 第128-130页 |
| ·Mass transfer coefficient | 第130-134页 |
| ·Component mass transfer rate crossing the interphase | 第134-135页 |
| ·Heat transfer coefficient and heat transfer rate crossing the interphase | 第135-141页 |
| ·Effective interphase area | 第141-146页 |
| Chapter Ⅴ:Conclusion and perspect | 第146-151页 |
| ·Conclusion | 第146-148页 |
| ·Perspect | 第148-151页 |
| PUBLICATIONS | 第151-152页 |
| BIBLIOGRAPHY | 第152-166页 |
