| 摘要 | 第3-6页 |
| ABSTRACT | 第6页 |
| Chapter1.Research process of pillararenes | 第9-41页 |
| 1.1 Introduction | 第9-11页 |
| 1.2 Synthesis of pillararenes | 第11-21页 |
| 1.2.1 Synthesis of pillar[5]arenes | 第12-15页 |
| 1.2.2 Synthesis of pillar[n]arenes | 第15-17页 |
| 1.2.3 Supposed mechanism for the formation of pillararenes | 第17-21页 |
| 1.2.4 Separation and purification of pillararene | 第21页 |
| 1.3 Structure of pillararenes | 第21-29页 |
| 1.3.1 Skeleton structure and cavity size of pillararene | 第21-24页 |
| 1.3.2 Conformation and planar chirality of pillararene | 第24-29页 |
| 1.4 Functionalization of pillararenes | 第29-32页 |
| 1.4.1 Functionalization of pillararene before cyclization | 第29-30页 |
| 1.4.2 Dealkylation and functionalization after the cyclization of pillararene | 第30-31页 |
| 1.4.3 Functionalization of pillar[5]arenes after cyclization and oxidation-reduction | 第31-32页 |
| 1.5 The host-guest poperties of pillararenes | 第32-41页 |
| 1.5.1 Host-guest properties of per-alkoxy pillararenes | 第32-38页 |
| 1.5.2 Host-guest properties of hydrophilic pillararenes | 第38-41页 |
| Chapter2.(propargyl)_5-Pillar[5]arene | 第41-55页 |
| 2.1 Introduction | 第41-46页 |
| 2.1.1 Introduction to RD-BMpillar[5]arene and RD-EMpillar[5]arene | 第41-43页 |
| 2.1.2 Applications of RD-pillar[5]arene | 第43-46页 |
| 2.2 Analysis and purification of(propargyl)5-pillar[5]arene isomers | 第46-51页 |
| 2.2.1 General | 第46-47页 |
| 2.2.2 Analysis of(propargyl)_5-pillar[5]arene isomers | 第47页 |
| 2.2.3 Purification of the four(propargyl)5-pillar[5]arene isomers by solvents washing | 第47-49页 |
| 2.2.4 Purification of the four(propargyl)5-pillar[5]arene isomers by prep-HPLC | 第49-51页 |
| 2.3 Identification of(propargyl)_5-pillar[5]arene isomers | 第51-53页 |
| 2.4 HPLC analysis of(propargyl)_5-pillar[5]arene in different reaction conditions | 第53-55页 |
| Chapter3.Synthesis of Rim-differentiated C_5-Synmetric Pillar[5]arene | 第55-69页 |
| 3.1 Synthesis of(propargyl)_5(methyl)5-pillar[5]arene as model compound | 第55-59页 |
| 3.1.1 Conventional statistical synthesis of(propargyl)_5(methyl)_5-pillar[5]arene | 第56-57页 |
| 3.1.2 Our preoriented synthesis of(propargyl)_5(methyl)_5-pillar[5]arene | 第57-59页 |
| 3.2 Optimization of the preoriented synthetic protocol of(propargyl)_5(methyl)_5-pillar[5]arene | 第59-60页 |
| 3.3 Synthesis of various C_5-synmmetric RD-pillar[5]arenes | 第60-63页 |
| 3.4 Mechanism/ Reaction pathways discussions of C_5-synmmetric RD-pillar[5]arenes forming | 第63-67页 |
| 3.5 Conclusion | 第67-69页 |
| Chapter4.Experimental Section | 第69-99页 |
| 4.1 General | 第69页 |
| 4.2 General synthetic procedures with spectroscopic data | 第69-88页 |
| 4.3 Single crystal tables | 第88-99页 |
| References | 第99-105页 |
| Achievement | 第105-107页 |
| Acknowledgements | 第107页 |
