| List of Figures, Schemes and Tables | 第6-8页 |
| Abstract | 第8页 |
| Chapter 1 General Introduction | 第9-23页 |
| 1.1 Conceptual Development of Tetrathiafulvalene Chemistry | 第9-10页 |
| 1.2 TTF as building blocks in supramolecular chemistry | 第10-15页 |
| 1.2.1 Crown-ether annelated TTFs as cation sensors | 第10-11页 |
| 1.2.2 molecular switches | 第11-12页 |
| 1.2.3 TTF as a mediator for chemical reaction | 第12-14页 |
| 1.2.4 Inclusion complexes of C_60 | 第14-15页 |
| 1.3 Synthesis of Tetrathiafulvalene Macrocycles | 第15-20页 |
| 1.3.1 General Introduction | 第15页 |
| 1.3.2 General procedure for synthesis of TTF macrocycles | 第15-18页 |
| 1.3.3 Bismacrocycles | 第18-20页 |
| 1.4 The aim and contents of our work | 第20-21页 |
| 1.5 The structure of my paper | 第21-23页 |
| Chapter 2 Synthesis of Crown Ether Derivatives of 1,3-dithiole-2-thione-4,5-dithiolate (DMIT) | 第23-34页 |
| 2.1 The design of crown ether derivatives of DMIT | 第23-25页 |
| 2.2 General procedure for synthesis of target compound | 第25-28页 |
| 2.2.1 Synthesis of bis (2-iodoethyl) ether (31) | 第25页 |
| 2.2.2 Synthesis of tetraethylammonium salt of Na_2DMIT zinc chelate (TEA_2[Zn(DMIT)_2](34) | 第25-26页 |
| 2.2.3 Synthesis of 4,5-bis (2-alkylthio)-1,3-dithiole-2-thione (35) | 第26页 |
| 2.3.4 Synthesis of 4,5-bis (2-alkylthio)-1,3-dithiole-2-ones (36) | 第26-27页 |
| 2.2.5 Synthesis of 4-(2-cyanoethylthio)-5-[2-(2-iodoethoxy)ethylthia]-1,3-dithiol-2-thione (37) | 第27页 |
| 2.2.6 synthesis of Bis[4-(2-cyanoethylthio)-1,3-dithiol-2-thione-2-ylthio] ether (38) | 第27页 |
| 2.2.7 Synthesis of Tetrakis(1,3-dithiol-2-thione) liner (39) | 第27-28页 |
| 2.2.8 Synthesis of Tetrakis(1,3-dithiol-2-thione) rnacrocycle (40) | 第28页 |
| 2.3 Experiment | 第28-32页 |
| 2.4 Results and conclutions | 第32-34页 |
| Chapter 3 Synthesis of Oligomeric Tetrathiafulvalene Macrocycles | 第34-48页 |
| 3.1 The design of oligomeric tetrathiafulvalene macrocycles | 第34-35页 |
| 3.2 The general procedure for preparation of target compounds | 第35-37页 |
| 3.2.1 Synthesis of 2,3-bis (2-cyanoethylthio)-6,7-bis (alkylthio) tetrathiafulvalene (41b-c) | 第35-36页 |
| 3.2.2 2-(2-Cyanoethylthio)-3-(5-iodoetherthio)-6,7-bis(methylthio) tetrathiafulvalene (42b-c) | 第36页 |
| 3.2.3 1,5-bis[3-(2-cyanoethylthio)-6,7-bis(2-methylthio)tetrathiafulvalene-2-ylthio]-2-ether (43b-c) | 第36-37页 |
| 3.2.4 Synthesis of tetrakis(tetrathiafulvalene) (44b-c) | 第37页 |
| 3.2.5 Synthesis of tetrakis(tetrathiafulvalene) (45b-c) | 第37页 |
| 3.3 Experiment | 第37-42页 |
| 3.4 Results and conclusion | 第42-48页 |
| 3.4.1 UV Spectrum studies of compound (45b) | 第43-44页 |
| 3.4.2 Preparation of single crystals from compound 45c and C_60 | 第44页 |
| 3.4.3 Electrochemical studies of compounds 44c and 45c | 第44-48页 |
| Conclusion | 第48-49页 |
| References and notes | 第49-53页 |
| Acknowledgement | 第53-54页 |
| Appendix: some spectra of the compounds | 第54-70页 |
