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Cellulose Derivative and Lanthanide Complex Thin Film

Dedication第5-6页
摘要第6-9页
Abstract第9-12页
List of Abbreviations第20-21页
Chapter 1 Introduction第21-47页
    1.1 Motivation第21-22页
    1.2 Aims and Outline of Thesis第22-24页
    1.3 Background and Information第24-47页
        1.3.1 Cellulose第24-32页
            1.3.1.1 Cellulose Structure第25-26页
            1.3.1.2 Cellulose Derivatives第26-31页
            1.3.1.3 Applications of Cellulose and Derivatives第31-32页
        1.3.2 Lanthanide Ions第32-36页
            1.3.2.1 Physical Properties of Lanthanide Ions第33页
            1.3.2.2 Chemical Properties of Lanthanide Ions第33-34页
            1.3.2.3 Lanthanide Ions Coordination Polymers第34-35页
            1.3.2.4 Application of Lanthanide Ions第35-36页
                1.3.2.4.1 Industrial Applications第35页
                1.3.2.4.2 Medical Applications第35页
                1.3.2.4.3 Fluorescence第35-36页
        1.3.3 Thin Film Fabrication第36-47页
            1.3.3.1 Definition of Thin Film第36页
            1.3.3.2 Layer by Layer Assembly Technique第36-37页
            1.3.3.3 Preparation Method of Thin Film第37-39页
                1.3.3.3.1 Dipping Coating第37-38页
                1.3.3.3.2 Spray Coating第38-39页
                1.3.3.3.3 Spin Coating第39页
            1.3.3.4 Growth Mechanism in Layer by Layer Films第39-41页
                1.3.3.4.1 Linear Growth第40-41页
                1.3.3.4.2 Exponential Growth第41页
            1.3.3.5 Properties of Polymer Complex Thin Film第41-42页
                1.3.3.5.1 Film Wettability第41页
                1.3.3.5.2 Mechanical Property第41-42页
            1.3.3.6 Application of Polymer Complex Thin Films第42-47页
                1.3.3.6.1 Bioactive and Biomimetic Coating第43页
                1.3.3.6.2 Buildup of Cell adhesive or Anti-Adhesive Films第43-44页
                1.3.3.6.3 Tissue Engineering第44页
                1.3.3.6.4 Drug Delivery System第44-45页
                1.3.3.6.5 Anti-Reflection Coating第45-46页
                1.3.3.6.6 Anti-Fogging Coating第46-47页
Chapter 2 Characterization of Complexes formed between Carboxymethylcellulose and Lanthanide ions第47-62页
    2.1 Introduction第47-48页
    2.2 Experimental第48-53页
        2.2.1 Materials第48页
        2.2.2 Complex Colloidal Particles第48-49页
        2.2.3 Weight Ratio第49页
        2.2.4 Characterization第49-53页
            2.2.4.1 Ultraviolet -Visible spectroscopy (UV-Vis)第49-50页
            2.2.4.2 Zeta potential measurement第50-51页
            2.2.4.3 Dynamic Laser-light Scattering (DLS)第51-52页
            2.2.4.4 Fourier transform infrared spectroscopy (FTIR)第52-53页
    2.3 Results and Discussion第53-61页
        2.3.1 Preparation of CMC-Ln Complex Colloidal Particles第53-61页
            2.3.1.1 Weight Ratios and p H value第53-55页
            2.3.1.2 Particle Size and Zeta-potential of CMC-Ce Complex第55-58页
            2.3.1.3 Coordination Bonds between CMC and Ln Ions第58-61页
    2.4 Chapter Summery第61-62页
Chapter 3 Cellulose Derivative-Lanthanide Complex film with Hierarchical Assembly Process第62-82页
    3.1 Introduction第62-64页
    3.2 Experimental第64-69页
        3.2.1 Materials第64页
        3.2.2 The Film Fabrication第64页
        3.2.3 Characterization第64-69页
            3.2.3.1 Fourier transform infrared (FTIR)第64页
            3.2.3.2 Optical Reflectometry第64-66页
            3.2.3.3 Fluorescence spectroscopy第66-67页
            3.2.3.4 Atomic-force microscopy (AFM)第67-69页
    3.3 Result and Discussion第69-81页
        3.3.1 The homogenous Solution of CMC-Ce第69-70页
        3.3.2 Thin film Fabrication of CC and CMC-Ln Complex第70-81页
            3.3.2.1 Luminescence of Films第75-78页
            3.3.2.2 The post Treatment of [CC/(CMC-Ce)]30 Film第78-81页
    3.4 Chapter Summary第81-82页
Chapter 4 Permeation of Lanthanide Ions on thin Film surface of cellulose derivatives第82-90页
    4.1 Introduction第82-83页
    4.2 Experimental第83-86页
        4.2.1 Materials第83-84页
            4.2.1.1 Cationic cellulose第83页
            4.2.1.2 Carboxymethyl cellulose第83-84页
            4.2.1.3 Cerium (III) Chloride Heptahydrate第84页
        4.2.2 Preparation of thin Film第84页
        4.2.3 Permeation of Lanthanide Ions into [CC/CMC]30 Film第84页
        4.2.4 Characterization第84-86页
            4.2.4.1 Ultraviolet -Visible Spectroscopy (UV-Vis)第84页
            4.2.4.2 Fluorescence Spectroscopy第84页
            4.2.4.3 Polarized light Microscope第84-86页
    4.3 Results and discussion第86-89页
        4.3.1 Interpenetration of lanthanide ions第86-87页
        4.3.2 Fluorescence properties of [CC/CMC]30 film after immersion第87-88页
        4.3.3 optical microscope of [CC/CM]30 film after immersion第88-89页
    4.4 Chapter Summary第89-90页
Chapter 5第90-104页
    5.1 Main Conclusion第90-92页
        List of Publication第91-92页
    5.2 Recommendation第92-93页
    5.3 Acknowledgment第93-94页
    5.4 Reference第94-104页

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