| Abstract | 第5-6页 |
| 摘要 | 第7-9页 |
| TABLE OF CONTENTS | 第9-12页 |
| LIST OF TABLES | 第12页 |
| LIST OF SCHEMES | 第12-14页 |
| LIST OF FIGURES | 第14-17页 |
| CHAPTER Ⅰ:INTRODUCTION | 第17-24页 |
| 1.1 Preparation of benzoxazine | 第17-19页 |
| 1.2 Preparation of benzoxazine-amide | 第19页 |
| 1.3 PROBLEMATICS | 第19-21页 |
| 1.4 HYPOTHESIS | 第21页 |
| 1.5 OBJECTIVES | 第21-24页 |
| CHAPTER Ⅱ:LITERATURE REVIEW | 第24-50页 |
| 2.1 INTRODUCTION | 第24-26页 |
| 2.2 Synthesis of allyl containing Benzoxazine Monomers | 第26-31页 |
| 2.2.1 Factors affecting benzoxazine synthesis | 第26-27页 |
| 2.2.2 Synthesis of Allyl containing benzoxazine | 第27-31页 |
| 2.3 Preparations of blends and composites based allyl containing benzoxazine | 第31-36页 |
| 2.3.1 Glass-fiber-Reinforced Allyl-benzoxazine composites | 第31-32页 |
| 2.3.2 Polyhedral oligomeric silsesquioxane(POSS)with allyl containing benzoxazine monomer | 第32-34页 |
| 2.3.3 Epoxy resin with allyl containing benzoxazine monomer | 第34页 |
| 2.3.4 Benzoxazine containing allyl group with bismaleimide | 第34-35页 |
| 2.3.5 Organoclay-Modified Allyl-Functional Benzoxazine Resin | 第35-36页 |
| 2.4 Polymeric Benzoxazine precursors | 第36-37页 |
| 2.5 Preparation of polymer with Benzoxazine moieties | 第37-40页 |
| 2.5.1 Oligosiloxanes Containiing Allyl-benzoxazine Moieties in the Main Chain | 第37-38页 |
| 2.5.2 Polysiloxane Containing Allyl-benzoxazine Moieties in the Main Chain | 第38-39页 |
| 2.5.3 Methacrylate with ally containing benzoxazine monomer | 第39-40页 |
| 2.6 Polymerization mechanism | 第40-45页 |
| 2.6.1 Curing behavior of monofunctional benzoxazine | 第43-44页 |
| 2.6.2 Curing behavior of bifunctional benzoxazine | 第44-45页 |
| 2.7 Properties of polybenzoxazines based allyl and their blends and composites | 第45-48页 |
| 2.7.1 Benzoxazine monomers containing ally1 group;ortho-allylphenol derivative | 第45-46页 |
| 2.7.2 Allyl containing bifunctional benzoxazine monomer:o-allyl bisphenol-A derivative | 第46页 |
| 2.7.3 Benzoxazine monomers containing allyl group;allylamine derivative | 第46-47页 |
| 2.7.4 Allyl containing bifunctional benzoxazine monomer:allylamine derivative | 第47页 |
| 2.7.5 Naphthoxazine monomers containing allyl | 第47-48页 |
| 2.8 Conclusion | 第48-50页 |
| CHAPTER Ⅲ:SYNTHESIS AND CHARACTERIZATION OF POLYfACRYLAMIDE-BENZOXAZINE):LOW ENERGY THERMAL POLYMERIZATION | 第50-60页 |
| 3.1 Introduction | 第50-51页 |
| 3.2 Experimental | 第51-52页 |
| 3.3 Characterization | 第52-53页 |
| 3.4 Results and Discussions | 第53-56页 |
| 3.5 Thermal and mechanical properties of Poly (acrylamide-beiizoxaziiie)s | 第56-57页 |
| 3.6 Conclusion | 第57-60页 |
| CHAPTER Ⅳ:THERMAL INDUCED REACTIVE COPOLYMERIZATION OF ALLYLBENZOXAZINE AND ACRYLAMIDE-BENZOXAZINE | 第60-76页 |
| 4.1. Introduction | 第60-62页 |
| 4.2. Polymerization of benzoxazine structure | 第62-63页 |
| 4.3. Experimental | 第63-64页 |
| 4.4. Results and discussion | 第64-74页 |
| 4.4.1 Characterization of polymer structures | 第64-67页 |
| 4.4.2 Reactivity of the monomers | 第67-68页 |
| 4.4.3 Copolymerization analysis by FTIR | 第68-69页 |
| 4.4.4 Analysis of Copolymerization by DSC | 第69-71页 |
| 4.4.5 Oxazine ring polymerization versus allyl group polymerization | 第71-72页 |
| 4.4.6 Copolybenzoxazines thermal stability | 第72-74页 |
| 4.5 Conclusion | 第74-76页 |
| CHAPTER Ⅴ:EFFECT oF MOIETIES ON THE CURING PROCESS:COPOLYMERIZATION OFPOLYBENZOXAZINES | 第76-108页 |
| 5.1 Introduction | 第76-77页 |
| 5.2 EXPERIMENTAL | 第77-79页 |
| 5.2.1 Materials | 第77页 |
| 5.2.2 Characterization | 第77页 |
| 5.2.3 Preparation of Bis(4-dodecyl-3,4-dihydro-2H-1,3-benzoxazine)(P-da) | 第77页 |
| 5.2.4 Preparation of allyl-benzoxazine | 第77-78页 |
| 5.2.5 Preparation of Bis(3,4-dihydro-2H-1,3-benzoxazine)anline(PB) | 第78页 |
| 5.2.6 Copolymerization of benzoxazines | 第78-79页 |
| 5.3 RESULTS AND DISCUSSION | 第79-107页 |
| 5.3.1 Structure characterization | 第79-82页 |
| 5.3.2 Copolymerization of benzoxazines | 第82-83页 |
| 5.3.3 Copolymerization of P-ala with P-da | 第83-88页 |
| 5.3.4 Copolymerization of P-ala with PB | 第88-93页 |
| 5.3.5 Copolymerization of PB with P-da | 第93-96页 |
| 5.3.6 Copolymerization analysis by FTIR | 第96-102页 |
| 5.3.7 Thermal stability of the copolybenzoxazines | 第102-107页 |
| 5.4 CONCLUSION | 第107-108页 |
| CHAPTER Ⅵ:LOWERING POLYPROPYLENE FLAMMABILITY BY POLYBENZOXAZINE:Synergistic Effect with MRP Flame Retardant | 第108-115页 |
| 6.1 Introduction | 第108-109页 |
| 6.2 Experiment | 第109-111页 |
| 6.3 Testing | 第111页 |
| 6.4 Resullts and Discussion | 第111-114页 |
| 6.5 Conclusion | 第114-115页 |
| REFERENCES | 第115-131页 |
| DEDICACE | 第131-132页 |
| ACKNOWLEDGEMENTS | 第132-133页 |
| 答辩委员会对论文的评定意见 | 第133页 |
